STUDY OF POLYCONDENSATION PROCESS TO RECEIVE BIODEGRADABLE POLYMERS

Givi Papava; Ia Chitrekashvili; Marina Gurgenishvili; Nazi Gelashvili; Ketevan  Papava; Ketevan  Archvadze

doi:10.31435/rsglobal_ws/30062022/7835

Givi Papava Professor, Doctor, Chief Scientific researcher, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia https://orcid.org/0000-0002-8837-4909
Ia Chitrekashvili Doctor, Senior researcher, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia
Marina Gurgenishvili Doctor, Chief Scientific researcher, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia https://orcid.org/0000-0002-2272-8380
Nazi Gelashvili Doctor, scientific worker, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia
Ketevan Papava Doctor, Senior researcher, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia https://orcid.org/0000-0002-5212-9362
Ketevan Archvadze Doctor, Senior researcher, TSU Petre Melikishvili Institute of Physical and Organic Chemistry, Tbilisi, Georgia https://orcid.org/0000-0002-7796-4137

DOI: https://doi.org/10.31435/rsglobal_ws/30062022/7835

Keywords: Spatial Structure, Linearstructure, Peptide Bond, Microorganisms, Biodegradable, Prolongedaction, Synthesis, Temperature, Catalyst.

Abstract

Biodegradation of polymers of spatial structure is complicated at the impact of soil destructive microorganisms and biodegradation requires a long time. We have implemented a target-oriented synthesis of a polymer to receive linear structure polymers where labile peptide bonds are preserved. To implement target-oriented synthesis of a polymer and to determine optimal conditions for reaction mechanism we studied the process of kinetics and its regularities – reaction temperature, duration, components ratio, concentration, reaction speed constant, and activation energy. The Arrhenius factor and succession of the introduction of initial components to the reaction medium were computed, and catalyst nature and other properties were determined. A high effect of prolongation was achieved, when carbamide and formaldehyde molar ratio were 1:1. In this case linear structure polymer is formed where peptide -CH2 – NH – are preserved.

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STUDY OF POLYCONDENSATION PROCESS TO RECEIVE BIODEGRADABLE POLYMERS

Abstract

References

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