IONITES ON THE BASIS OF CLINOPTILOLITE

  • Givi Papava Professor, Doctor, Georgia, Tbilisi, Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi State University
  • Marina Gurgenishvili Doctor, Georgia, Tbilisi, Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi State University
  • Ia Chitrekashvili Doctor, Georgia, Tbilisi, Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi State University
  • Eter Gavashelidze Doctor, Georgia, Tbilisi, Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi State University
  • Gelashvili Nazi Doctor, Georgia, Tbilisi, Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi State University
Keywords: Ionite, ionogen group, zeolite, clinoptillolite, cationite, polymerization

Abstract

Organomineral ionites have been synthesized, in which natural mineral sorbent is chemically bound to organic part of a molecsule, containing ionogen groups. Ionogen groups of these ionites contribute to efficient exchange in water solutions. They might be used for cleaning drainage waters and technical solutions, as well as for purification of medicinal preparations from various admixes. Hydrogen forms of natural zeolite - clinoptilolite and bromoacetic acid were used to resolve this problem. Chemical modification of clinoptilolite, by inculcation of ionogen groups into zeolite skeleton, enables us to increase significantly ionite exchange capacity. Static exchange capacity of a cationite with carboxyl ionogen groups increases from 0,1 - 0,9 (for chemically unmodified zeolite) to 5- 6 мg.equiv./g.

References

D. C. Freeman, D.N. Stamires. J. Chem. Phys., 35, N 3, 799, 1961.

G.Sh. Papava, B.M. Mgeladze, K.P. Papava, N.S. Dokhturishvili, N.A. Maisuradze, E.Sh. Gavashelidze. Cationites on the basis of zeolites. Bulletin of Acad.Sci. GSSR, 114, No 2, 1984, p.303-306.

O.M. Mdivnishvili, L.V.Makharadze. Bulletin of Acad.Sci., GSSR, 65, No 2.

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Published
2019-10-31
Citations
How to Cite
Givi Papava, Marina Gurgenishvili, Ia Chitrekashvili, Eter Gavashelidze, & Gelashvili Nazi. (2019). IONITES ON THE BASIS OF CLINOPTILOLITE. International Academy Journal Web of Scholar, (10(40), 39-41. https://doi.org/10.31435/rsglobal_wos/31102019/6740

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