HYDRO ISOLATION MATERIALS, LUMINOPHORE AND OTHER DEFICIENT PRODUCTS, INNOVATIVE TECHNOLOGY

. One of the main objectives of the project is to develop a methodology for obtaining high quality water-proofing materials. The abovementioned high-melting tar mass will be used as the main raw material. Especial treatment and further homogenization of the mass – mixture of high-dispersive quartz sand, silicates and other wastes – gives possibility to make various universal and inexpensive compositions. With the aim to improve hydro-insulating and other specific characteristics of the compositions they will be varied by changing the ratio of ingredients. The elasticity of these compositions is conditioned by macromolecular paraffin-ceresin and the polymeric (rubber) components; varying the strength and adhesion is possible by soluble and insoluble silicate-quartz components. The mentioned components can be got in a large amount in region. Therefore, products obtained from cheap raw materials will be inexpensive. The use of the mentioned waste is also important to avoid the pollution of nature. Operating characteristics of the proposed luminophore satisfy requirements of international standarts. In particular, the solutions made from it have an ability to detect invisible cracks of the thick < 1 mm. The light intensity in its greenish-yellow area is 4,5-5 times more than that of standard uranyl nitrate. It is stable with high quantum efficiency (40-45%). KEYWORDS

petrolatum, luminophore and different types of bitumens from oil, on the basis of which it is possible to produce small-scale deficient inexpensive products [1].
The production of the above-mentioned materials from the local raw materials and various types of waste is highly relevant in Georgia.
To this end, the first step is to create laboratory and experimental modeling methods as a basis for the future production technologies.
The strategic goal of the project is to create zero-discharge treatment schemes for organic and mineral wastes to produce various types of deficient products in Georgia and, in addition, to avoid pollution of the environment [2].
The project proposal deals with the preparation of various compositions of hydroinsulation materials from inorganic components and oil waste in Georgia. It is also taken into account the separation of luminophore, paraffin-ceresin and bitumen masses of various types from the wastes in pipelines. The latter will be used as one of the components in waterproofing compositions.

Materials and methods.
All used chemicals were of analytical grade. AFP Silica gel (activated fine porous silica gel)manufacturer: Labstatus Ltd (Ukraine); Petroleum ether (Sigma-Aldroch International GmbH, Germany).
Research results.
The purpose of the project is to create the basis for the production of hydroinsulating materials and small-scale deficient, high-quality products -paraffin and ceresin, petrolatum, luminophore, lubricants and bitumens for various purposes.
The novelty is the use of sedimentary waste in the oil pipeline to produce small-scale deficient and expensive products such as: [3] 1. Paraffin (C 25 -C 35; melt temperature 50-65 0 C and more) and ceresin (C 36 -C 53 ; melt temperature is whithin the range 50-65 0 C), which are of great demand for industrial and domestic purposes; 2. luminophoric component is needed to detect invisible cracks with the methods of luminescent marking and luminescence microscopy; 3. High-melting tar mass is needed to obtain raw insulation materials (water-proofing and anticorrosive ones), electrode coke and high-melting bitumen. This is also important to avoid pollution of the environment [4]. Calculations showed that the use of waste is reasonable and economically profitable if the content of the oil components is more than 30%. The Baku-Tbilisi-Ceyhan oil pipeline contains 60-75% and more oil components. Therefore, separation of the above-mentioned products from the waste for the further use is prospective to produce cheap materials.
The project plan provides fractioning of sedimentary waste in the oil pipeline and clearing fractions without using traditional, expensive stages and adsorbents, catalysts and reagents. Specifically, melting of sediment and fractionation of viscous mass is provided by rectification (under atmospheric pressure) and molecular distillation ( 5. Fraction > 450 ℃ -raw material to obtain electrode coke, water-proofing materials, bitumens and luminescence components, etc. [5]; 6. Two more fractions: 450-500 ° C (for obtaining high quality luminophore) and 500-550 °C (for obtaining high quality electrode coke) will be got by distillation of remaining viscous mass.

Conclusions.
The 5th fraction (> 450 ℃), and the residue left after the molecular distillation are to be used as the main component for preparing the test waterproofing compositions. Then the highly dispersed secondary organic components (polimeric and/or rubber) and also highly dispersed inorganic components (sand, gravel), then soluble glass (silicate solution) and other special additives will be added. Finally, these mixtures will be homogenized at the temperature 60-75 ℃ and intensive stirring.
Obtaining of different samples of test hydro-insulation compositions is planned by varying the component mass ratio and the type and quantity of specific additives. The study of mechanical and the physical and chemical parameters of each sample will allow us to select the optimal composition of the insulation material according to the specifics of its use.
The preparation of insulation materials for the following purposes is provided: • Waterproofing of concrete, ferroconcrete, metal, wood and other construction structures; filling and bonding of cracks; • Flat roofing; • Isolation of pipelines, including oiland gas pipelines (hydro-and anti-corrosive isolation).